phosphate reaction in boiler waterbest stainless steel tubing cutter

-:Hv3tDbJ$8 :# 'GP`{Wu D;=4iDi-)!7!g If impurities enter the boiler feedwater or corrosion develops inside the boiler, equipment can be damaged, the plant can experience unexpected downtime, and energy creation can be extremely ineffective. Compared with PT, it avoids phosphate hide-out and problems with monitoring and control. While he is well-versed in all Sentry products and applications, he is particularly focused on the food and beverage and power generation markets as well as emerging market development. It is still necessary to limit the chloride in the boiler water to prevent hydrogen damage. Condensate makeup is not required to be demineralized which can cause buildup of these impurities in boilers. xb```f``Id`e``5bd@ A6 daS$>nxtgbr 0000102220 00000 n 0000004136 00000 n Selective pearlite corrosion and possible, incipient hydrogen damage were associated. Departure from nucleate boiling (DNB) and steam blanketing in generating bank tubes have resulted, causing treatment chemicals to precipitate, deposit, and react on the internal. Phosphate corrosion in high pressure boilers, CO boiler reliability: examination of failure mechanisms, root causes, corrective actions and monitoring required, Phosphate corrosion in high-pressure boilers, Caustic corrosion of convection tubing in a waste-heat boiler. hTP1n0 Chemical-reducing substances. Heat flux rates have increased in critical sections of the boiler with consequent disruption in thermal hydraulic flow in water and steam circuits. Chemical treatment in industrial boilers can be complicated due to: Process steam carries heat from cogeneration plants. As operating pressures increased, the frequency of corrosion-related failures in phosphate-treated boilers also increased. Caustic attack, resulting from excessive gas-side heat flux relative to the internal coolant flow rate, was found. Choosing the appropriate treatment depends on a variety of factors, including boiler design and pressure, the effectiveness and reliability of the makeup water treatment system and the risk of impurity ingress and iron oxide carryover from condensate return. Phosphate attack as caustic corrosion in high-pressure boiler tubes, 360105* - Metals & Alloys- Corrosion & Erosion. These materials include scavenger chemicals or corrosion inhibitors injected into the boiler or boiler feedwater. o% G3fx6si9h.-rj/I[?H0ft*$=t:@w&)Q R,1GobL~+AX-2J(ard0o45BWZgG,(msiC\h N ~Q[&/#FN|[n-N gOukcz&.V=38(O2gn3!om=h$Q%^DI}%kQfvL9LzU !j %PDF-1.4 % Steam & Water. 0000000016 00000 n 0000003581 00000 n Micro-Raman spectroscopy was used for the first time to confirm the presence of maricite when investigating the root cause of generating bank tube failures. Chelants, such as ethylenediaminetetraacetic acid (EDTA), sometimes can be used to bind with metals to keep them suspended. 0000060263 00000 n 0000001822 00000 n YX\5wb ,=#P:7FzQA|LXUX&cX^dEI?C/?la`%y;f=n~5Z,|*3i:=nG(^|*yv0tOFNv^CrxH Unfortunately, conventional congruent control did not take into account the interaction of phosphate compounds with deposits and corrosion products, including iron oxides on boiler tube surfaces, and corrosion continued. This steam delivers the latent heat to the manufacturing process, leaving liquid condensate. Phosphate corrosion is the name given to attack involving phosphate compounds having unique wastage morphologies and associated corrosion products and deposits. The paper also discusses the use of the latest Electrical Power Research Institute guidelines for failure mechanism identification in boiler tubes and for monitoring cycle chemistry. 0000088218 00000 n However, corrosion occurred in the new high pressure plant, due to hydrogen damage and caustic gouging. For example, in steam generators that commonly operate at or below 600 psi, uncatalyzed or catalyzed sodium sulfite (Na2SO3) is a non-volatile oxygen scavenger that adds inorganic dissolved solids to the feedwater. FFS are a range of corrosion-inhibiting products for boiler chemistry, including film-forming amines (FFAs). The engineered changes required to correct the combustion and thermal hydraulic problems are described, as well as the rationale for introducing equilibrium phosphate treatment as the boiler water chemistry control corrective action. Its also recommended that sludge conditioners using water-soluble polymers can help keep solids in suspension by a combination of dispersion, crystal modification and sequestration, in addition to phosphate treatment. 0 Any Application, As Upgrading feed rates have increased, the volume flow rate, and properties of the streams have changed to such extent that the boilers have suffered severe reliability problems due to the new, and adverse fireside conditions. surfaces of the water wall tubes. 0000020372 00000 n %%EOF Many medium- to high-pressure boiler systems, including carbon steel boilers, suffer from corrosion and impurities. rm6t.l"iFk(9[;nD|n`uSZaDbau{ lqS6@`'U2 Hn cs+l0Fpo: Analysis results, conclusions, and recommendations to the plant are discussed. Phosphate corrosion is the name given to attack involving phosphate compounds having unique wastage morphologies, associated corrosion products and deposits. }WjFGyIW=l+2|H!2]#nGK2TkqDt:?l7pu^fQ;Osg*={R_keOP'xRg8X8]!OZ,te?/+?C(zMf'nx#u Y'.ag@"DHar(3H|J/clia n(+g3' K^>mOX3+su;H*j!aV&d0 *{MAQ@Am/bDWx y?Xu0'^5WZ3ijxmV70)?JKnT/VZv3Lp'Q0\8 gV-M*NsSB.zA0:e"79=%q:VJ?}(' __^% 89L'v1$6+0~nc4eD# The benefits of {open_quotes}OH{close_quotes}. Boiler water can be treated with several agents, including a phosphate/polymer combination, polymers alone, and (rarely) chelating agents. An example is a 1,300 psi (9 MPa) and 930 F (500 C) boiler. 0000102008 00000 n 0000008167 00000 n NlV,/94/y?)\9VtJ9hspeP"dY!Gu+[&L This paper discusses the use of computational fluid dynamic simulation and other techniques to assess water and fireside conditions for the original, current, and future operating conditions (prior to and post boiler design modifications). 0000002982 00000 n 0000003544 00000 n 2. 0000007118 00000 n 0000019918 00000 n Theoretically, the condensate should be clean water. :x&L:~i*xY(hf[TdC 148 37 Congruent phosphate control was derived to prevent the formation of free caustic by feeding orthophosphates to maintain a boiler water sodium-to-phosphate ratio at which theory surmised free caustic could not form. g,.%E\#/1K@Cb@R@vS"1EQI7D53et+S+P*q4..bkD6J]Et]#%@ghD,VyUu aI1zULJ @CI%Aah 8:: \q,!+HL4(HB3]G![~s!1]A[)Y+(U. A Steam and Water Analysis System (SWAS) comprised of properly selected sample conditioning equipment and on-line instrumentation is key to controlling and monitoring your system treatment regime. Sentry can provide insight on the best solution for your plant, including SWAS and single line options. Once a treatment is chosen, monitoring chemistry Is the best way to ensure the treatment is working appropriately. 0000002228 00000 n Its critical to limit impurities and corrosion in a boiler system to maximize boiler output and prevent these challenges. Trisodium phosphate (Na3PO4), also known as TSP, is a common boiler water conditioning chemical that establishes moderately alkaline conditions in the boiler to minimize corrosion and reduce scaling where hardness ingress occurs. startxref <<60FB01378AEBC7448D78B6BE7EF2A14B>]>> However, chelants should be used only with well-deaerated feedwater, excellent pre-treatment control and low feedwater iron concentrations. Industrial steam plants and combined steam and power facilities, also known as cogeneration plants, commonly use boilers to provide high-quality steam and electric power. hXr}W#"G_T[[%2y#1pt H$*$fzO>wPoe(BY"?)Kd!4E&7}&@,+!/DT'K^;&Ne,_W)Y$-s- As operating pressures have increased, the frequency of corrosion-related failures in phosphate-treated boilers has also increased. 0000008024 00000 n 0000087950 00000 n This is referred to as phosphate corrosion. 148 0 obj <> endobj This led to sodium hydroxide being abandoned in the USA in favour of phosphate treatment (PT). trailer Industrial boiler water treatment helps protect low-pressure steam generators often found in co-generation plants. ;{\di&s1c->D.uxj+-nj2,|NAYCl g?,@z.vC8hS{6Um]=pfr:S+&Skq6Q^ {Zu7Kf endstream endobj 149 0 obj <> endobj 150 0 obj <> endobj 151 0 obj <>/Font<>/ProcSet[/PDF/Text]/ExtGState<>>> endobj 152 0 obj <> endobj 153 0 obj <> endobj 154 0 obj <> endobj 155 0 obj <> endobj 156 0 obj [/ICCBased 168 0 R] endobj 157 0 obj <>stream 0000001036 00000 n Some sodium hydroxide needs to be present in the boiler water to achieve the full benefits of {open_quotes}OH{close_quotes} treatment, but the concentration has to be strictly limited to reduce the risk of caustic gouging in the boiler, carry-over into the steam and damage to superheaters, reheaters and turbines. 0000001907 00000 n 0000088443 00000 n products, including iron oxides on boiler tube surfaces. Phosphate treatment programs use blends of tri- di- and monosodium phosphate for pH control as well. 0000004214 00000 n 0000020167 00000 n Sludge conditioners can also help keep iron particles in suspension for subsequent blowdown. xref Four finned, convection tubes from a 450 psi (3,1 MPa) waste-heat boiler at a chemical processing plant were examined to determine the cause of severe internal gouging corrosion. endstream endobj 158 0 obj <> endobj 159 0 obj <> endobj 160 0 obj <> endobj 161 0 obj <>stream Maricite is one of the definitive corrosion products resulting from acid phosphate corrosion. A chemical-reducing agent can lower dissolved oxygen levels to prevent or minimize corrosion within the boiler and turbines. hbspt.cta._relativeUrls=true;hbspt.cta.load(532305, '1466073b-4775-4785-b94a-81779404607c', {"useNewLoader":"true","region":"na1"}); Topics: But in practice, the processing system introduces contaminants into the liquid stream and condensate return, including iron, copper, ammonia, magnesium, calcium and organic carbon. 3. 0000092769 00000 n 0000003867 00000 n Many failures were attributed to ``free`` caustic generated by the nonstoichiometric precipitation of various phosphate compounds on boiler surfaces. As the heart of the plant, these boilers are crucial to efficient energy creation. {open_quotes}OH{close_quotes} treatment is simpler. Congruent control was devised to prevent the formation of free caustic by feeding orthophosphates so as to maintain a boiler water sodium to phosphate ratio in a range where theory surmised free caustic could not form. John has worked with clients worldwide to help them to comply with regulations and optimize processes by applying proper sampling hardware and techniques. This produces unique wastage morphologies and characteristic corrosion products of NaFePO[sub 4]. Precipitation was caused by inadequate heat flow inducing a departure from nucleate boiling (DNB), steam blanketing, and deposits. John Powalisz, Director of International Sales, is dedicated to sharing his technical expertise and knowledge of sampling equipment and systems in power plants, refineries, chemical and food processing facilities garnered from more than 19 years with the company. 0000008468 00000 n Additionally, corrosion and cooling/heating equipment can help maintain purified water with little contaminants from materials. High concentrations of sodium phosphate and sodium hydroxide were used for conditioning drum boilers in the 1950`s. The Importance of Industrial Boiler Water Treatment, Sentry can provide insight on the best solution for your plant, including, Understanding the Challenges in HRSG Water and Steam Monitoring, The Advantages of Chlorine Dosing to Control Biofilm, Impurity ingress from steam feed and condensate return systems, Impurities, such as hardness, from inadequate makeup water treatment system performance, Condensate return system corrosion that damages piping and equipment, and sends iron oxide corrosion to the boiler, which can deposit and reduce effective heat transfer. Caustic corrosion produces well-defined depressions or gouges, as does phosphate attack at lower sodium-to-phosphate ratios. treatment over all volatile treatment (AVT), include a higher tolerance to chloride in the boiler water and a reduced risk of acid attack. ,BO:|AP%hiBhR feNH >d* Mjo In addition, heavy mineral deposits restrict heat transfer. These factors must be evaluated carefully for each plant, as a standardized approach can lead to serious problems. Lx:?2h#9m$AH|-6Ut[mZDf&XZ= 0000078279 00000 n The introduction of water impurities to the boiler can lead to higher conductivity, increasing corrosion potential. Limiting chloride ingress and the use of low concentrations of sodium hydroxide ({open_quotes}OH{close_quotes} treatment) was developed and now is used successfully for more than 50,000 MWe of plant. This is achieved by continuous monitoring the feedwater, boiler water and steam. E8@;? 0000092537 00000 n Contact us at +1-262-567-7256, orcomplete our online contact formfor more information. 0000011162 00000 n 0000004468 00000 n 1. 0000003120 00000 n ey&g/; Some boiler-tube failures attributed to caustic gouging actually have been caused by reaction of sodium phosphate species with boiler tube steel, boiler tube oxides, or both. Organic cycle chemistry based on FFS is being increasingly employed as an alternative to conventional treatment programs because they inhibit corrosion while maintaining clean heat transfer surfaces. Corrosion continued to occur even when sodium to phosphate-pH control ranges were maintained according to theory. (L20'ui% [ 0!!(&M990Zus=73lVe7U@s"@N.(t30K i& v % cUd TrxzE4P`Qbr%4qIkV:{JhNMti:oNs+|]$ All of these contaminants negatively affect the feedwater systems, boilers and turbines in the plant, potentially causing unnecessary downtime and equipment damage. FFS inhibit corrosion by forming a very thin, non-wetable film on the surface of power plant equipment, which acts as a barrier between the metal surface and the water/steam phase to help reduce corrosion. 0000006984 00000 n Phosphate treatments have been used in boilers for more than 70 years. The chemical guidelines for {open_quotes}OH{close_quotes} treatment adopted overseas are reviewed, together with the evidence gained from operating plant, the problems that occurred and how these were overcome, EPRI guidelines are proposed for coal fired plant. Theyre often delivered via injection equipment, such as atomizers or sample quills. 0000007723 00000 n EUF]+s&. 184 0 obj <>stream Boiler water treatment. Unfortunately, conventional congruent control did not take into account the interaction of phosphate compounds with various deposits and corrosion, The waste gas streams from upgrading processes pass as primary energy sources to two CO boilers. 0000092985 00000 n 0000007500 00000 n 0000101755 00000 n 0000002361 00000 n Problems of control and corrosion with PT led to a search for alternative methods of conditioning in other countries. Film-forming substances (FFS). 0000002041 00000 n The boiler tubes, made of ASTM A 178 GrC, failed by precipitation of the phosphates used for the chemical treatment of the boiler water, coupled with contamination of the condensate with alkaline salts.